Websites:
1) http://www.gotdotnet.com - Look at the tutorials for WinForms, WebForms, and Common Tasks.
2) http://www.xtremedotnettalk.com
Books:
I've found all of the Microsoft Press books extremely helpful. Specifically,
Programming Visual Basic.NET
ADO.NET
Coding Techniques For Visual Basic.NET
also, if you don't have any real OO experience (ie. you're coming from VB6) then...
OOP with Visual Basic.NET and C#.NET
General Advice: Search the forums prior to asking questions.